state whether it is possible to determine whether one polymer has a higher melting temperature than the other

 

For each of the following pairs of polymers, do the following: (1) state whether it is possible to determine whether one polymer has a higher melting temperature than the other; (2) if it is possible, note which has the higher melting temperature and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why.

(a) Isotactic polystyrene that has a density of 1.12 g/cm3 and a weight-average molecular weight of 150,000 g/mol; syndiotactic polystyrene that has a density of 1.10 g/cm3 and a weight-average molecular weight of 125,000 g/mol

(b) Linear polyethylene that has a degree of polymerization of 5000; linear and isotactic polypropylene that has a degree of polymerization of 6500

(c) Branched and isotactic polystyrene that has a degree of polymerization of 4000; linear and isotactic polypropylene that has a degree of polymerization of 7500

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